Consider a CSV file with the following contents:
$ cat file Unix,10,A Linux,30,B Solaris,40,C Fedora,20,D Ubuntu,50,E1. To insert a new column (say serial number) before the 1st column
$ awk -F, '{$1=++i FS $1;}1' OFS=, file
1,Unix,10,A
2,Linux,30,B
3,Solaris,40,C
4,Fedora,20,D
5,Ubuntu,50,E
$1=++i FS $1 => Space is used to concatenate columns in awk. This expression concatenates a new field(++i) with the 1st field along with the delimiter(FS), and assigns it back to the 1st field($1). FS contains the file delimiter.